Pali-Casanova, Ramón and González, Wadi Elim Sosa and Zavala Loría, José del Carmen and García, Asteria Narváez and Yam Cervantes, Marcial Alfredo and Vega, Manuel de Jesús Aguilar and Dzul Lopez, Luis UNSPECIFIED, UNSPECIFIED, UNSPECIFIED, UNSPECIFIED, UNSPECIFIED, UNSPECIFIED, luis.dzul@unini.edu.mx (2021) Structure and kinetic rigidity of polymers as related to chain relaxations. Journal of Thermoplastic Composite Materials, 34 (5). pp. 596-613. ISSN 0892-7057
Full text not available from this repository.Abstract
Kinetic rigidity of several polymers such as 2,6-bis(3-aminophenoxy)benzonitrile/4,4′oxydiphthalic anhydride (β-CN)APB/ODPA, poly[(2,2-dimethyl-1,3-dioxolan-4-yl)methyl acrylate)] (PACGA), and diglycidyl ether of bisphenol A (DEGEBA) was studied. Rigidity parameter D, Vogel’s temperature T0, and the activation energy Uα (Tg) for the glass transition were evaluated through Vogel’s model along with relaxation data using “nonlinear” regression of Arrhenius function. The existence of certain functional groups within the structure, such as the aromatic rings, gives high level of kinetic rigidity to the structure as is the case of (β-CN)APB/ODPA and DEGEBA, while the aliphatic groups confer flexibility, as in PACGA.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | Kinetic, rigidity, Vogel’s model, glass transition, activation energy |
| Subjects: | Subjects > Engineering |
| Divisions: | Ibero-american International University > Research > Scientific Production |
| Depositing User: | Sr Bibliotecario |
| Date Deposited: | 20 May 2022 13:48 |
| Last Modified: | 31 May 2022 07:37 |
| URI: | http://repositorio.funiber.org/id/eprint/2016 |
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